Benzodiazoboroles as stabilizers for hydrocarbon polymers

ABSTRACT

STABILIZING ORGANIC SUBSTRATES AGAINST DETERIORATION DURING TRANSPORTATION, STORAGE AND/OR USE BY INCORPORATING THEREIN A 2-HYDROCARBYL-1,3-DI-SECALDKYL OR DI-CYCLOALKYL2H-1,3,2-BENZODIAZOBOROLE.

United States Patent O 3,629,190 BENZODIAZOBOROLES AS STABILIZERS FOR HYDROCARBON POLYMERS Allen K. Sparks, Des Plaines, Ill., assignor to Universal Oil Products Company, Des Plaines, Ill.

N Drawing. Continuation-impart of application Ser. No. 623,805, Mar. 17, 1967. This application July 22, 1969, Ser. No. 843,852

Int. Cl. C08c 11/66; C08d 11/64; C081. 45/60 US. Cl. 260-458 8 Claims ABSTRACT OF THE DISCLOSURE Stabilizing organic substrates against deterioration during transportation, storage and/or use by incorporating therein a 2-hydrocarbyl-1,3-di-secalkyl or di-cycloalkyl- 2H-1,3,2-benzodiazoborole.

CROSS REFERENCE TO RELATED APPLICATIONS This is a continuation-in-part of copending application Ser. No. 623,805 filed Mar. 17, 1967, now Patent 3,481,978 issued Dec. 2, 1969.

DESCRIPTION This invention relates to the stabilization of organic substrates by incorporating therein an additive comprising a particularly substituted benzodiazoborole.

The additive of the present invention is illustrated by the following formula R l N 1\2\ where R, and R are sec-alkyl or cycloalkyl, R" is hydrocarbyl, and Y is hydrogen, hydrocarbyl, hydrocarbyloxy, halogen or nitro.

It is an essential feature of the present invention that R and R are of secondary alkyl configuration or cycloalkyl. These compounds possess improved potency as additives to organic substrates. The sec-alkyl groups may contain from 3 to 20 carbon atoms each and thus will be selected from isopropyl, sec-butyl, sec-pentyl, sec-hexyl, sec-heptyl, sec-octyl, sec-nonyl, sec-decyl, sec-undecyl, sec-dodecyl, sec-tridecyl, sec-tetradecyl, sec-pentadecyl, sec-hexadecyl, sec-heptadecyl, sec-octadecyl, sec-nonadecyl and sec-eicosyl. The cycloalkyl groups may contain from 3 to 12 carbon atoms each and, in a particularly preferred embodiment, comprises cyclohexyl.

Referring to the above formula, R is hydrocarbyl and will be selected from alkyl, alkaryl, aryl, aralkyl or cycloalkyl. The alkyl moiety may be of primary, secondary or tertiary configuration and will contain from 1 to 20 carbon atoms or more. Where R" is aryl, it will be selected from phenyl, naphthyl, anthracyl, etc. and may contain alkyl substituents attached to the aryl nucleus. Thus, the alkaryl groups may comprise toluene, ethyl benzene, propyl benzene, etc. in which the alkyl moiety contains up to about 20 carbon atoms. Also the alkaryl substitution may contain two alkyl groups attached to the aryl nucleus and thus may include Xylene, diethyl benzene, dipropyl benzene, etc. in which each alkyl group may contain from 1 to 20 carbon atoms and may be the same or of a different number of carbon atoms and/or configuration. Where R" is aralkyl, illustrative groups include benzyl, phenylpropyl, ph'enylbutyl, phenylpentyl, phenylice hexyl, phenylheptyl, phenyloctyl, etc. which group also may contam one or two alkyl substituents attached to the phenyl nucleus. Where R" is cycloalkyl, the alkyl group contains from 3 to 12 carbon atoms in the ring and thus will be selected from cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl, cycloundecyl and cyclododecyl. Here again, cyclohexyl is particularly preferred.

Where Y is hydrocarbyl, it may be selected from those hereinbefore specifically set forth. Where Y is hydrocarbyloxy, it may comprise alkoXy or phenoxy, the latter also may contain alkyl substituents attached to the phenyl nucleus. The hydrocarbyl moiety of the hydrocarbyloxy group will be selected from the hydrocarbyl groups hereinbefore specifically set forth. Where Y is halogen, it will be selected from chlorine, bromine, fluorine or iodine, preferably being chlorine or bromine.

Illustrative preferred compounds of the present invention include 2-nonyl-1,3-di-sec-heXyl-2H-1,3,2-benzodiazoborole, 2-nonyl-1,3-di-sec-heptyl-2H-1,3 ,2-benzodiazoborole, 2-nonyl-1,3-di-sec-octyl-2H-1,3,2-benzodiazoborole, 2-nonyl-1,3-di-sec-nonyl-2H-1,3,2-benzodiazoborole, 2-nonyl- 1,3 -di-sec-decyl-2H-1,3,2-benzodiazoborole, 2-nonyl-1,3-di-sec-undecyl-2H-1,3,2-benzodiazoborole, 2-nonyl-1,3-di-sec-dodecyl-2H-1,3,2-benzodiazoborole,

etc and corresponding compounds in which the 2-nonyl group is replaced by propyl, butyl, pentyl, hexyl, heptyl, octyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, otacdecyl, nonadecyl, eicosyl, etc. As hereinbefore set forth, the R" substitution may be of primary, secondary or tertiary alkyl configuration.

In another preferred embodiment, R" is phenyl and illustrative compounds include 2-phenyl-1,3-di-sec-heXyl-2H-1,3 ,2-benzodiazoborole, Z-phenyl-1,3-di-sec-heptyl-2H-1,3,2-benzodiazoborole, 2-phenyl-1,3-di-sec-octyl-2H-1,3 ,2-benzodiazoborole, Z-phenyl-1,3-di-sec-nonyl-2H-1,3 ,Z-benzodiazoborole, 2-phenyl-1,3-di-sec-decyl-2H- 1,3 ,Z-benzodiazoborole, Z-Phenyl-l,3-di-sec-undecyl-2H- 1,3 ,Z-benzo diazoborole, Z-phenyl-1,3-di-sec-dodecyl-2H-1,3,2-benzodiazoborole,

etc. In another embodiment the phenyl group is replaced by naphthyl and illustrative compounds will correspond to those set .forth above except that the phenyl group will be replaced by naphthyl.

The compounds of the present invention are prepared in any suitable manner. In a particularly preferred method, o-phenylenediamine is subjected to reductive alkylation with a ketone in the presence of hydrogen to form N,N-di-sec-alkyl-o-phenylenediamine, which then is reacted with an alkyl or aryl boronic acid. In preparing the N,N-di-sec-alkyl'o-phenylenediarnine, the ketone used in the reductive alkylation will be selected to produce the desired sec-alkyl derivatives. For example, the di-isopropyl derivative is prepared using acetone as the ketone, the di-sec-butyl derivative is prepared by using methyl ethyl ketone, the di-sec-pentyl derivative is prepared by using methyl propyl ketone or diethylketone, etc. The dicyclohexyl derivative is prepared by using cyclohexanone as the ketone. The reductive alkylation is effected in any suitable manner and, in a preferred method, the reaction is etfected in the presence of a reductive alkylation catalyst. The reductive alkylation catalyst includes those containing nickel, molybdenum, platinum, palladium, etc. A preferred catalyst comprises a composite of alumina and 0.5 to 10% by weight of platinum, which catalyst may or may not contain from about 0.1 to 5% by weight of chlorine and/or fluorine. At least two mole proportions of ketone per mole proportion of o-phenylenediamine is used and preferably an excess of ketone is employed in order to insure that the desired reductive alkylation is effected and this excess may range up to 40 mole proportions of ketone per 1 mole proportion of o-phenylenediamine.

The N,N'-di-sec-alkyl-o-phenylenediamine or dicycloalkyl derivative prepared in the above manner is then reacted with alkyl or phenyl boronic acid. The reaction preferably is effected in the presence of a solvent. Any suitable solvent may be employed and preferably is an aromatic solvent, including benzene, toluene, xylene, ethyl benzene, cumene, etc. The temperature of reaction will vary with the particular solvent and may be within the range of from 80-300 C. The reaction is effected by refluxing the mixture of reactants and solvent for a sufficient time to effect completion of the reaction, which time may be within the range of from about 2 to 24 hours or more. The water formed during the reaction preferably is continuously removed. Following completion of the reaction, the novel compound of the present invention may be recovered in admixture with the solvent, or the solvent may be removed by distillation, preferably under vacuum, or in any other suitable manner.

The novel compound of the present invention generally will comprise a heavy liquid and may be used as such, but preferably will be used in solution in a suitable solvent which may include the solvent used in the reaction or it may be a different solvent. In any event the solvent will be selected to be compatible with the organic substrate into which the novel compound is to be incorporated. The solvent may be selected from hydrocarbons and particularly aromatics, as hereinbefore set forth, or paraflinic hydrocarbons including pentane, hexane, heptane, nonane, decane, etc., cycloparaffins and particularly cyclohexane, etc. The compounds of the present invention may be used in a concentration in the solvent of from to 80% and preferably from to 70% by weight thereof.

The novel compounds of the present invention will have varied utility. In general, these compounds are useful as additives to retard deterioration of organic substrates which normally tend to deteriorate in storage, transportation and/or in use due to oxidation, ozonation, ultraviolet light absorption and/or other reactions.

In one embodiment, the compounds of the present invention are particularly useful in the stabilization of lubricants including lubricating oils and greases. These may be either synthetic or of petroleum origin. The synthetic lubricating oils are of varied types including aliphatic esters, polyalkylene oxides, silicones, esters of phosphoric and silicic acids, highly fluorine-substituted hydrocarbons, etc. Of the aliphatic esters, di-(Z-ethylhexy1)sebacate is being used on a comparatively large commercial scale. Other aliphatic esters include dialkyl azelates, dialkyl suberates, dialkyl pimelates, dialkyl adipates, dialkyl glutarates, etc. Specific examples of these esters include dihexyl azelate, di-(2-ethylhexyl)-azelate, di-3,5,5-tri-methylhexyl glutarate, di-3,5,5-trimethylpentyl glutarate, di-(Z-ethylhexyl)-pimelate, di-(Z-ethylhexyl)-adipate, tri-amyl tricarballylate, pentaerythritol tetracaproate, pentaerythritol tetrapelargonate, dipropylene glycol dipelargonate, 1,5-pentanediol-di-(2-ethylhexanonate), etc. The polyalkylene oxides include polyisopropylene oxide, polyisopropylene oxide diether, polyisopropylene oxide diester, etc. The silicones include methyl silicone, ethylphenyl silicone, etc. and the silicates include, for example, tetraisooctyl silicate, etc. The highly fiuorinated hydrocarbons include fiuorinated oil, perfluorohydrocarbons, etc.

Additional synthetic lubricating oils include (1) neopentyl glycol esters, in which the ester group contains from 3 to 12 carbon atoms or more, and particularly neopentyl glycol propionate, neopentyl glycol butyrate, neopentyl glycol caproate, neopentyl glycol caprylate,

neopentyl glycol pelargonate, etc., (2) trialkylol alkane esters such as the esters of trimethylol alkanes including trimethylol ethane, trimethylolpropane, trimethylolbutane, trimethylolpentane, trimethylolhexane, trimethylolheptane, trimethyloloctane, trimethylolnonane, trimethyloldecane, trimethylol, undeeane, trimethyloldodecane, etc., and particularly triesters in which the ester portions each contain from 3 to 12 carbon atoms and may be selected from those hereinbefore specifically set forth in connection with the discussion of the neopentyl glycol esters, and (3) tricresylphosphate, triphenylphosphate, trioctylphosphate, trinonylphosphate, tridecylphosphate, as well as mixed aryl and alkyl phosphates, etc.

The lubricating oils of petroleum origin include those referred to as motor lubricating oil, railroad type lubricating oil, marine oil, transformer oil, turbine oil, transmission oil, differential oil, diesel lubricating oil, gear oil, cutting oil, rolling oil, cylinder oil, hydraulic oil, slushing oil, specialty products oil, etc.

The synthetic greases generally are referred to as lithium base grease, sodium base grease, calcium base grease, barium base grease, strontium base grease, aluminum base grease, etc. These greases are solid or semi-solid gels and, in general, are prepared by the addition to mineral and/or synthetic oil of hydrocarbon-soluble metal soaps or salts of higher fatty acids as, for example, lithium stearate, calcium stearatc, aluminum naphthenate, etc. The grease may contain thickening agents such as silica, carbon black, polyacrylates, talc, etc. Another type of grease is prepared from oxidized petroleum wax, to which the saponifiable base is combined with the proper amount of the desired saponifying agent, and the resultant mixture processed to produce a grease. Other types of greases in which the features of the present invention are usable include petroleum grease, whale grease, wool grease, etc., and those made from inedible fats, tallow, butchers waste, etc.

In another embodiment, the novel compounds of the present invention are useful in the stabilization of polyolefins including polyethylene, polypropylene, polybutylene, copolymers of ethylene and propylene, copolymers of ethylene and butylene and copolymers of propylene and butylene, as well as polymers prepared from one or more higher molecular weight olefins. The polyolefins preferably are of high molecular weight, usually having a molecular Weight above 1000 and extending into the hundreds of thousand range. The polyolefins may be of the high density, medium density or low density type. Polyethylene is utilized, for example, as a thermoplastic molding or coating agent. Because of its high dielectric strength and its resistance to water, polyethylene is particularly advantageous for use as insulators or dielectrics in condensers and other similar electronic equipment. Polyethylene plastics also are used in many other applications. Polypropylene, polybutylene and copolymers of ethylene, propylene and/or butylene also are used in electronic equipment, as well as many other applications. The polyolefins also are subject to attack by atmospheric oxygen which impairs the desirable properties thereof.

In another embodiment, the compounds of the present invention are useful in the stabilization of rubber, which may be of natural or synthetic origin. Rubber is composed of conjugated 1,3-dienes, either as polymers thereof or as copolymers thereof with other polymerizable compounds, and the rubbers, both natural and synthetic, are included as substrates which may be stabilized in accordance with the present invention. Synthetic rubbers include SBR rubber (copolymer of butadiene and styrene), Buna N (copolymer of butadiene and acrylonitrile), butyl rubber (copolymer of butadiene and isobutylene), Neoprene rubber (chloroprene polymer), Thiokol rubber (polysulfide), silicone rubber, etc. The natural rubbers include hevea rubber, cautchouc, balata, gutta percha, etc. It is well known that rubber undergoes deterioration due to oxygen and ozone and, when exposed to direct sunlight for extended periods of time, also undergoes deterioration from this source.

Other organic substances which deteriorate in storage or during transportation include hydrocarbons and particularly motor fuels such as saturated and particularly unsaturated gasoline, blends of unsaturated and saturated gasolines, including cracked gasoline, straight run gasoline, polymer gasoline, coker gasoline, alkylate, etc. and mixtures thereof, as well as jet fuel, diesel oil, mineral oil, fuel oil, residual oil, drying oil, waxes, resins, etc. These substances are adversely aflected by oxygen, with the resultant formation of undesirable gum, discoloration and/or other deleterious reaction products.

When used as an additive in an organic substrate, the compound of the present invention may be used in a concentration of from about 0.001% to about and more particularly from about 0.001% to about 1% by Weight of the organic substrate. The exact concentration to be used will depend upon the particular organic substrate being stabilized.

It is understood that the compound of the present invention may be used along with other additives incorporated in the organic substance. For example, in grease it may be used along with higher alcohols, esters, organic amines, polybutene, sulfurized fatty materials, sulfur chlorine compounds molybdenum disulflde, dyes, perfumed materials, fillers, etc. In lubricating oil, it may be used along with one or more of the above additives and/ or viscosity index improver, pourpoint depressor, antifoaming agent, detergent, lubricity or extreme pressure additive, etc. In polymers, such as polyolefins, the compound is used along with one or more of dyes and/ or pigments, anti-static agents, plasticizers, other antioxidants or ultraviolet light stabilizers, etc. In some cases, it may be of advantage to also include a metal deactivator as, for example disalicylal diaminopropane, ethylene diamine tetraacetic acid tetrasodium salt, etc., or to include other additives such as tricresyl phosphate, trialkyl phenols including 2,6-di-tert-butyl-4-methylphenol, 2,4-climethyl-6- tert-butylphenol, alkylated diphenyl amines, phenyl naphthyl amines, dialkyl phenylenediamines, phenothiazine, organic selenium compounds, etc. When desired, the compound of the present invention may be prepared as a mixture with one or more of these other additives and incorporated in this manner in the organic substance.

The compound of the present invention may be incorporated in the organic substance in any suitable manner and at any suitable stage of preparation. For example, in an organic substance which comprises a mixture of several components as, for example, grease, the compound may be added to one or more of the components of the grease prior to compositing and processing thereof, or it may be added to the mix at any time preferably before final processing in order to obtain intimate mixing and dissolving of the compound in the grease.

The following examples are introduced to illustrate further the novelty and utility of the present invention, but not with the intention of unduly limiting the same.

Example I The compound of this example is 2-nonyl-l,3-di-secoctyl-2H-1,3,2-benzodiazoborole and was prepared by reacting nonyl boronic acid with N,N'-di-sec-octyl-o-phenylenediamine, the latter being prepared by reductive alkylation of o-phenylenediamine with octyl ketone at about 160 C., 100 atmospheres of hydrogen and in contact with an alumina-platinum catalyst. The reaction was effected by refluxing a mixture of 37 g. of N,N'-di-secoctyl-o-phenylenediamine, 23 g. of nonyl boronic acid and 250 cc. of benzene. The refluxing was continued for 6 hours, and 2.5 cc. of water was recovered from the distillation. Following completion of the reaction, 56 g. of 2-nonyl-l,3-di-sec-octyl 2H 1,3,2-benzodiazoborole was recovered as a reddish liquid. This corresponds to the theoretical yield of 56.9 g. Analysis of the product found a boron content of 2.35% by weight and basic nitrogen of 1.97 meq./ g. which equals a molecular weight of 507.6 and corresponds to the theoretical molecular weight of 513.5.

Example II The compound of this example is 2-phenyl-1,3-di-secbutyl-ZH-1,3,2-benzodiazoborole and is prepared by first subjecting o-phenylenediamine to reductive alkylation with methyl ethyl ketone and then reacting 1 mole proportion of the N,N-di-sec-butyl-o-phenylenediamine with phenyl boronic acid. The latter reaction is effected by refluxing the reactants in the presence of benzene solvent and removing the water formed in the reaction. After completion of the reaction \2-phenyl-l,3-di-sec-butyl2H- 1,3,2-benzodiazoborole is recovered in admixture with the benzene solvent and is utilized in this manner as an additive to organic substrates.

Example III The compound of this example is 2-cyclohexyl-ll,3-disec-hexyl-ZH-1,3,2-benzodiazoborole and is prepared by first subjecting o-phenylenediamine to reductive alkylation with ethyl propyl ketone to form N,N-di-sec-hexylo-phenylene diamine and then reacting the same with cyclohexyl boronic acid in the presence of toluene solvent under refluxing conditions for 8 hours. The 2-cyclohexyll ,3-di-sec-hexyl-2H- 1 ,3 ,Z-benzodiazoborole is recovered in admixture with the toluene solvent and is utilized in this manner.

Example IV The compound of this example is 2-decyl-1,3-di-cyclohexyl-2H-1,3,2-benzodiazoborole and is prepared by first reductively alkylating o-phenylenediamine with cyclohexanone to form N,N'-di-cyclohexyl-n-phenylenediamine and then reacting the same with decyl boronic acid in the presence of benzene solvent under refluxing conditions for 7 hours. The resultant 2-decyl-1,3-di-cyclohexyl- 2H-1,3,2-benzodiazoborole is recovered in admixture with the benzene solvent and is used in this manner as an additive.

Example V The compound of this example is 2-naphthyl-1,3-diisopropyl-2H-l,3,2-diazoborole and is prepared by first subjecting o-phenylenediamine to reductive alkylation with acetone and then reacting one mole proportion of the N,N-di-isopropyl-o-phenylenediamine with naphthyl boronic acid. The later reaction is effected by refluxing the reactants in the presence of xylene solvent and removing the water formed during the reaction. After completion of the reaction, Z-naphthyl-1,3-di-isopropyl-2H- -l,3,2-benzodia=zoborole is recovered in admixture with xylene solvent and is utilized in this manner as an additive to organic substrates.

Example VI The compound of this example is 2-cyclooctyl-1,3-distearyl-2H-l,3,2-benzodiazoborole and is prepared in substantially the same manner as described above by first subjecting o-phenylenediamine to reductive alkylation with ethylpentadecyl ketone and then reacting the same with cyclooctyl boronic acid in the presence of xylene solvent. The 2-cyclooctyl-l,3-di-stearyl-2H-1,3,2-benzodiazoborole is recovered in admixture with the solvent.

Example VII As hereinbefore set forth the novel compound of the present invention has utility as an additive to organic substrates which undergo deterioration during transportation, storage and/or use. This example illustrates the use of 2 nonyl-l,3-di-sec-octyl-2H-1,3,2-benzodiazoborole, prepared as described in Example I, as an additive in lubricating oil. The lubricating oil used in this example is a synthetic lubricating oil marketed under the tradename of Plexol 201 and is dioctyl sebacate.

The lubricaing oil was evaluated in accordance with a standard oxygen stability test in which a 100 cc. sample of the lubricating oil is placed in a batch maintained at 204 C. and air is blown therethrough at a rate of liters of air per hour. The test is continued for 48 hours. The kinematic viscosities at the start of the test, after 24 hours and after 48 hours were determined. In addition, the percent of isooctane insoluble materials was determined.

The following table reports the results of an evaluation of the control sample of the lubricating oil (not containing the additive) and a sample of the lubricating oil containing 2% by weight of 2-nonyl-1,3-di-scc-octyl-2H- 1,3,2-benzodiazoborole.

From the data in the above table it will be seen that the control sample of the lubricating oil (withont additive) underwent an increase of approximately 100% in kinematic viscosity. In contrast, the sample containing the additive underwent an increase of less then 10% in kinematic viscosity.

In the control sample, the percent of material insoluble in iso-octane was 8.2%. In contrast the percent of isooctane insolubles in the sample containing the additive was 0.1%. This again demonstrates the efiectiveness of the compound of the present invention to retard deleterious reactions in the lubricating oil during evaluation in the above manner.

Example VIII The compound prepared as described in Example I was also evaluated as an ultraviolet light absorber in polypropylene. The polypropylene samples were milled in a 2' roll heated mill of conventional commercial design and the additive, when employed, was incorporated in the sample during the milling. The samples were pressed into sheets of about 17 mil. thickness and cut into plaques of about 1 /3" x 1 /2. The plaques were inserted into plastic holders, afiixed onto a rotating drum and exposed to carbon arc rays at about 52 C. in a Fadeometer. The samples were examined periodically by infrared analysis to determine the carbonyl band at 1715 cm.- which is reported as the carbonyl number. The higher intensity of the carbonyl band indicates a higher carbonyl concentration (expressed as carbonyl number) and accordingly increased deterioration.

A sample of the polypropylene without inhibitor developed a carbonyl number of greater than 1000 within 120 hours of exposure in the Fadeometer. Another sample of polypropylene containing 0.5% by weight of 2-nonyl- 1,3 di sec octyl 2H 1,3,2 benzodiazoborole, prepared as described in Example I, did not develop a carbonyl number of greater than 1000 until about 240 hours of exposure in the Fadeometer.

Example IX This example illustrates the use of 2-cyclohexyl 1,3- di-sec-hexyl-ZH-1,3,2-benzodiazoborole, prepared as described in Example III, as an additive in rubber. The compound is incorporated in a concentration of 3% by weight into butadiene-styrene rubber during milling thereof. This serves to retard deterioration of the rubber during storage and use.

8 Example X This example illustrates the use of a compound of the present invention in gasoline. The additive of this example is Z-phenyl 1,3 di-sec-butyl 2H 1,3,2 benzodiazoborole, prepared as described in Example II, and is incorporated in a concentration of 0.02% in a thermally cracked gasoline. This serves to prolong the induction period of the gasoline.

I claim as my invention:

1. Organic substrate normally tending to undergo deterioration during transportation, storage or use due to at least one of oxidation, ozonation and ultraviolet light absorption selected from the group consisting of polyolefins and rubbery diene hydrocarbon polymers and containing, as an inhibitor against such deterioration, a stabilizing concentration of 2 hydrocarbyl-1,3 di C c -sec-alkyl 2H 1,3,2 benzodiazoborole or 2-hydrocarbyl 1,3 di-C -C -cycloalkyl 2H 1,2,3 benzodiazoborole.

2. The organic substrate of claim 1 in which the benzodiazoborole is of the following formula:

B RII l where R and R are sec-alkyl having from 3 to 20 carbon atoms or cycloalkyl having from 3 to 12 carbon atoms in the ring, and R" is selected from the group consisting of alkyl containing from 3 to 20 carbon atoms, phenyl, naphthyl and cycloalkyl having from 3 to 12 carbon atoms in the ring.

3. The organic substrate of claim 2 in which R" is alkyl containing from 4 to 12 carbon atoms, phenyl, naphthyl or cyclohexyl.

4. The organic substrate of claim 3 wherein the inhibitor is 2 nonyl 1,3 di-sec-octyl 2H 1,3,2 benzodiazoborole.

5. The organic substrate of claim 3 wherein the inhibitor is 2 phenyl 1,3 di-sec-butyl 2H 1,3,2- benzodiazoborole.

6. The organic substrate of claim 3 wherein the inhibitor is 2 cyclohexyl 1,3 di sec hexyl 2H 1,3,2 benzodiazoborole.

7. The organic substrate of claim 3 wherein the inhibitor is 2 decyl 1,3 di cyclohexyl 2H 1,3,2- benzodiazoborole.

8. The organic substrate of claim 1 being rubbery polymer of conjugated 1,3-diene hydrocarbon.

References Cited UNITED STATES PATENTS 2,952,645 9/1960 Groszos et a1. 26015 3,193,521 7/1965 Jasching 26045.8

3,296,190 1/1967 Reischl et al. 260-459 OTHER REFERENCES Scott: Atmospheric Oxidation and Antioxidants,

1965, pp. 308, 339 and 413.

DONALD E. CZAJ A, Primary Examiner R. A. WHITE, Assistant Examiner US. Cl. X.R. 260800 

